Basu, Amitabha ; Bhaduri, Sumit ; Khwaja, Hanif ; Jones, Peter G. ; Schroeder, Tina ; Sheldrick, George M. (1985) Preliminary communicationCatalytic olefin hydrogenation with nonacarbonyltris(triphenylphosphine)triruthenium and its derivatives. Crystal structure of [Ru2(CO)5(PPh3)(μ-PPh2)(μ-O=CPh)] Journal of Organometallic Chemistry, 290 (2). c19-c22. ISSN 0022-328X
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Official URL: http://dx.doi.org//10.1016/0022-328X(85)87440-4
Related URL: http://dx.doi.org/10.1016/0022-328X(85)87440-4
Abstract
The complexes [Ru3(CO)7(PPh2)2(C6H4)] and [Ru2(CO)5(PPh3)(μ-PPh2)(μ-O=CPh)] were obtained by pyrolysis of [Ru3(CO)9(PPh3)3] and tested as catalysts for the hydrogenation of cyclohexene and 2-cyclohexen-1-one. The structure of [Ru2(CO)5(PPh3)(μ-PPh2)(μ-O=CPh)] was established by a single crystal X-ray diffraction study.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 2090 |
| Deposited On: | 08 Oct 2010 09:13 |
| Last Modified: | 18 Jan 2011 05:07 |
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