Chakraborty, T. K. ; Dutta, S. (1998) Radical-induced opening of trisubstituted epoxides: application in the synthesis of C1-C12 segment of epothilones Tetrahedron Letters, 39 (1-2). pp. 101-104. ISSN 0040-4039
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...
Related URL: http://dx.doi.org/10.1016/S0040-4039(97)10442-7
Abstract
Diastereo- and regioselective opening of a trisubstituted epoxy ketone at the more substituted carbon using samarium(II) iodide presents an alternate approach to the C5-C7 aldol moiety with β-hydroxyketo framework in the stereoselective synthesis of C1-C12 segment of epothilones.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 20615 |
| Deposited On: | 20 Nov 2010 13:51 |
| Last Modified: | 23 May 2011 03:51 |
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