Chakraborty, Tushar K. ; Goswami, Rajib K. (2004) Synthesis of (3R,4S,5S,9S)-3,5,9-trihydroxy-4-methylundecanoic acid δ-lactone Tetrahedron Letters, 45 (41). pp. 7637-7639. ISSN 0040-4039
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2004.08.099
Abstract
Radical-mediated opening of a chiral trisubstituted epoxy alcohol using cp2TiCl furnished the '2-methyl-1,3-diol' moiety with the desired stereochemistry, which led to a total synthesis of (3R,4S,5S,9S)-3,5,9-trihydroxy-4-methylundecanoic acid δ-lactone 1.
Item Type: | Article |
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Source: | Copyright of this article belongs to Elsevier Science. |
Keywords: | (3R,4S,5S,9S)-3; 5; 9-Trihydroxy-4-methylundecanoic Acid; δ-Lactone; Sharpless Kinetic Resolution; Epoxide Opening; 2-Methyl-1; 3-diol |
ID Code: | 20563 |
Deposited On: | 20 Nov 2010 14:18 |
Last Modified: | 22 May 2011 15:04 |
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