Studies directed towards the total synthesis of clavosolides: synthesis of an isomer of clavosolide A

Chakraborty, Tushar Kanti ; Reddy, Vakiti Ramkrishna (2006) Studies directed towards the total synthesis of clavosolides: synthesis of an isomer of clavosolide A Tetrahedron Letters, 47 (13). pp. 2099-2102. ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2006.01.130

Abstract

The total synthesis of clavosolide A, employing a radical-mediated route to build its substituted tetrahydropyran unit, a Yamaguchi reaction to construct the diolide aglycon and the Schmidt method for the final glycosidation step, revealed that the reported structure is an isomer of the natural product.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Clavosolides; Clavosolide A; Epoxide Opening; 2-Methyl-1; 3-diol; Diolide
ID Code:20529
Deposited On:20 Nov 2010 14:22
Last Modified:20 Nov 2010 14:22

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