Field-optimized initial state-based selective control of IBr photodissociation

Bairagi, Deepa B. ; Gross, Peter ; Mishra, Manoj K. (1997) Field-optimized initial state-based selective control of IBr photodissociation Journal of Physical Chemistry A, 101 (5). pp. 759-763. ISSN 1089-5639

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Official URL: http://pubs.acs.org/doi/abs/10.1021/jp9615666

Related URL: http://dx.doi.org/10.1021/jp9615666

Abstract

A new scheme for controlling photodissociation through preparation of a variationally optimized linear superposition of field-free vibrational eigenstates is applied for selective control of IBr photodissociation. The dependence of IBr photodissociation on various field parameters and initial conditions is explored. In a broad range of field parameters, the product yield is shown to increase considerably when a photolysis pulse is applied to the variationally optimized linear combination as opposed to photolysis of IBr with the entire population in a single vibrational level. The frequency, intensity, and phase dependence of this enhancement is explored for both CW and Gaussian pulses.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:20281
Deposited On:20 Nov 2010 14:44
Last Modified:08 Jun 2011 04:36

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