Rajasekharan, M. V. ; Chandramouli, G. V. R. ; Manoharan, P. T. (1989) Polarized electronic spectral studies on some diethyldithiocarbamate complexes of Ni(II) and Pd(II) Chemical Physics Letters, 162 (1-2). pp. 110-116. ISSN 0009-2614
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/000926...
Related URL: http://dx.doi.org/10.1016/0009-2614(89)85076-6
Abstract
Polarized optical spectra of three planar low-spin d8 complexes, Ni(detc)2, NiCl(detc) (PPh3) and Pd(detc)2 (where detc is diethyldithiocarbamate and PPh3 is triphenylphosphine), are reported. The assignments of the spectral transitions were made based on the d-level ordering xy>yz>x2-y2⇒xz>z2. The observed spectral bands in all three complexes are correlated with each other.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 19896 |
| Deposited On: | 22 Nov 2010 11:42 |
| Last Modified: | 06 Jun 2011 12:23 |
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