Acharyya, Rama ; Peng, Shie-Ming ; Lee, Gene-Hsiang ; Bhattacharya, Samaresh (2003) An unprecedented oxidative migration of a methyl group from 2-(2′,6′-dimethylphenylazo)-4-methylphenol mediated by ruthenium and osmium Inorganic Chemistry, 42 (23). pp. 7378-7380. ISSN 0020-1669
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ic034968i
Related URL: http://dx.doi.org/10.1021/ic034968i
Abstract
An unprecedented chemical transformation of 2-(2′,6′-dimethylphenylazo)-4-methylphenol has been observed upon its reaction with [M(PPh3)3X2] (M = Ru, Os; X = Cl, Br) whereby one methyl group from the phenyl ring of the arylazo fragment migrates to the metal center via oxidation to CO.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 1917 |
| Deposited On: | 08 Oct 2010 11:30 |
| Last Modified: | 11 May 2012 11:11 |
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