Das, Atanu Kumar ; Sarkar, Biprajit ; Duboc, Carole ; Strobel, Sabine ; Fiedler, Jan ; Zalis, Stanislav ; Lahiri, Goutam Kumar ; Kaim, Wolfgang (2009) An odd-electron complex [Ruk(NOm)(Qn)(terpy)]2+ with two prototypical non-innocent ligands Angewandte Chemie International Edition, 48 (23). pp. 4242-4245. ISSN 1433-7851
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.20...
Related URL: http://dx.doi.org/10.1002/anie.200900767
Abstract
Six combinations of oxidation states are conceivable for the paramagnetic title complex. Single-crystal X-ray diffraction, spectroscopic analysis (IR, EPR at conventional and high frequency), and DFT calculations establish that it is the iminosemiquinone radical structure that is formed: [Ruk(NOm)(Qn)(terpy)]2+ (k=2+, m=1+, n=1-).
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
| Keywords: | Nitrosyl Complexes; Non-innocent Ligands; Quinones; Radical Ligands; Ruthenium |
| ID Code: | 19143 |
| Deposited On: | 23 Nov 2010 13:26 |
| Last Modified: | 26 Feb 2011 04:04 |
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