Ghumaan, Sandeep ; Lahiri, Goutam Kumar (2006) Tuning intermetallic electronic coupling in polyruthenium systems via molecular architecture Journal of Chemical Sciences, 118 (6). pp. 537-545. ISSN 0253-4134
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Official URL: http://www.ias.ac.in/chemsci/Pdf-Nov2006/537.pdf
Related URL: http://dx.doi.org/10.1007/BF02703951
Abstract
A large number of polynuclear ruthenium complexes encompassing selective combinations of spacer (bridging ligand,BL) and ancillary (AL) functionalities have been designed. The extent of intermetallic electronic communication in mixed-valent states and the efficacy of the ligand frameworks towards the tuning of coupling processes have been scrutinised via structural, spectroelectrochemical, EPR, magnetic and theoretical investigations. Moreover, the sensitive oxidation state features in the complexes of non-innocent quinonoid bridging moieties have also been addressed.
Item Type: | Article |
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Source: | Copyright of this article belongs to Indian Academy of Sciences. |
Keywords: | Polynuclear Ruthenium Complexes; Mixed Valency; Electronic Coupling; Spectroelectrochemistry; DFT Calculations |
ID Code: | 19139 |
Deposited On: | 23 Nov 2010 13:26 |
Last Modified: | 17 May 2016 03:45 |
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