Facile formation of hexahydroporphyrin complexes by reduction of octaethylisobacteriochlorinnickel(II)

Lahiri, Goutam K. ; Stolzenberg, Alan M. (1993) Facile formation of hexahydroporphyrin complexes by reduction of octaethylisobacteriochlorinnickel(II) Angewandte Chemie International Edition, 32 (3). pp. 429-432. ISSN 1433-7851

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.19...

Related URL: http://dx.doi.org/10.1002/anie.199304291

Abstract

Under extremely mild conditions (room temperature) the hexahydroporphyrin 2 isomerizes to its tautomer 3. Complex 2 is the first metal complex with a 2,3,7,8,15,23-hexahydroporphyrin as ligand and is synthesized from 1 by reduction with sodium amalgam.

Item Type:Article
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ID Code:19138
Deposited On:23 Nov 2010 13:26
Last Modified:06 Jun 2011 05:54

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