Sarkar, Biprajit ; Patra, Srikanta ; Fiedler, Jan ; Sunoj, Raghavan B. ; Janardanan, Deepa ; Mobin, Shaikh M. ; Niemeyer, Mark ; Lahiri, Goutam Kumar ; Kaim, Wolfgang (2005) Theoretical and experimental evidence for a new kind of spin-coupled singlet species: isomeric mixed-valent complexes bridged by a radical anion ligand Angewandte Chemie International Edition, 44 (35). pp. 5655-5658. ISSN 1433-7851
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.20...
Related URL: http://dx.doi.org/10.1002/anie.200501075
Abstract
Valencies get remix: A unique kind of electronic structure (Mn+0.5)(μ-L.-)(Mn+0.5) which was previously discussed only for metal-ligand charge-transfer (MLCT) excited states is established structurally and by quantum chemical analysis for both rac (see picture) and meso isomers of [(μ-abpy){Ru(acac)2}2] (abpy=2,2'-azobispyridine, acac-=acetylacetonate).
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
| Keywords: | Azobispyridine; Bridging Ligands; Mixed-valent Complexes; N Ligands; Ruthenium |
| ID Code: | 19013 |
| Deposited On: | 25 Nov 2010 14:36 |
| Last Modified: | 26 Feb 2011 04:24 |
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