Hydrochlorination of methanol to methyl chloride in fixed catalyst beds

Thyagarajan, M. S. ; Kumar, Rajinder ; Kuloor, N. R. (1966) Hydrochlorination of methanol to methyl chloride in fixed catalyst beds Industrial and Engineering Chemistry Process Design and Development, 5 (3). pp. 209-213. ISSN 0196-4305

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Official URL: http://pubs.acs.org/doi/abs/10.1021/i260019a001?pr...

Related URL: http://dx.doi.org/10.1021/i260019a001

Abstract

The vapor phase hydrochlorination of methanol to methyl chloride in fixed beds with silica gel-alumina (88 to 12) and γ-alumina catalysts was studied in a glass tubular reactor in the temperature range of 300° to 390°C. Of the two catalysts studied, γ-alumina gave nearly equilibrium conversions under the experimental conditions. The data are expressed in the form of second-order irreversible rate equations for both the catalysts studied.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:18466
Deposited On:17 Nov 2010 09:06
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