Krishnamurthy, S. S. ; Ramachandran, Kolikkara ; Vasudeva Murthy, A. R. ; Shaw, Robert A. ; Woods, Michael (1980) Studies of phosphazenes. Part 10. Spirocyclic derivatives of cyclotriphosphazatrienes Journal of the Chemical Society, Dalton Transactions (5). pp. 840-844. ISSN 0300-9246
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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1980...
Related URL: http://dx.doi.org/10.1039/DT9800000840
Abstract
The reactions of hexachlorocyclotriphosphazatriene, N3P3Cl6, and its geminal bis-t-butylamino- and diphenyl derivatives, with ethylenediamine and ethanolamine are reported. In each case, both chlorine atoms attached to the same phosphorus atoms are replaced, giving rise to spirocyclic derivatives. A small quantity of a bis spirocyclic derivative, N3P3(NHCH2CH2O)2Cl2, is also obtained; this compound occurs in both cis and trans forms. Attempts to prepare fully substituted tris spirocyclic derivatives have been unsuccessful and only resinous materials were obtained. The 1H and 31P n.m.r. spectra of the products are discussed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 17839 |
| Deposited On: | 16 Nov 2010 12:37 |
| Last Modified: | 08 Jun 2011 07:17 |
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