Kumara Swamy, K. C. ; Ramabrahmam, P. ; Krishnamurthy, S. S. (1985) Studies of phosphazenes: Part 271. Synthesis of (triphenylphosphazenyl)pentachloro and pentafluoro-cyclotriphosphazenes Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 15 (8). pp. 1023-1035. ISSN 1553-3174
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Official URL: http://www.informaworld.com/index/762708244.pdf
Related URL: http://dx.doi.org/10.1080/00945718508060632
Abstract
The triphenylphosphazenyl cyclophosphazene, N3P3(N=PPh3)Cl5 (1) has been prepared by two new methods using Appel and Staudinger reactions. The effect of solvent on the synthesis of 1 from the reaction of gem-N3P3 (NH2)2Cl4 with Ph3PCl2 (Kirsanov method) has been investigated. The fluoro compound, N3P3(N=PPh3)F5(2), is obtained readily in good yields (85%) by the treatment of 1 with KF in methyl cyanide.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Taylor and Francis Ltd. |
| ID Code: | 17826 |
| Deposited On: | 16 Nov 2010 12:38 |
| Last Modified: | 17 Jul 2012 00:26 |
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