Job, V. A. ; Kartha, S. B. ; Singh, Kuldip ; Kartha, V. B. (1987) Inversion-rotation interaction in NH2D: intensity perturbations in the ν2 band Journal of Molecular Spectroscopy, 126 (2). pp. 290-306. ISSN 0022-2852
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002228...
Related URL: http://dx.doi.org/10.1016/0022-2852(87)90238-4
Abstract
The parameters of NH2D in the ground and ν2 states have been refined by a simultaneous analysis of the microwave, FTIR, and diode laser data. The intensities of 46 NH2D lines have been measured, and from a least-squares fit of the intensity data the a ← s, s ← a, s ← s, and a ← a transition moments have been derived. The intensities of the lines in the ν2 band of NH2D have been calculated taking into account the inversion-rotation interaction. The accuracies of the wavenumbers and intensities calculated with the new parameters are estimated to be better than ±0.0002 cm-1 and ±5%, respectively. The matrix elements for interaction of vibrations through x, y, and z axis couplings are appended.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 17825 |
| Deposited On: | 16 Nov 2010 12:38 |
| Last Modified: | 03 Jun 2011 11:37 |
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