Katti, K. V. ; Krishnamurthy, S. S. ; Woods, Michael (1985) Studies of phosphazenes Part XXVI: Bi(cyclophosphazenes) containing a P-O-P bridge Phosphorus, Sulfur, and Silicon and the Related Elements, 25 (2). pp. 167-171. ISSN 1042-6507
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Official URL: http://www.informaworld.com/index/767953113.pdf
Related URL: http://dx.doi.org/10.1080/03086648508072730
Abstract
Penta(phenoxy)chlorocyclotriphosphazene [N3P3 (OPh)5Cl (1)] reacts with "(hydroxy)" phosphazenes, N3P3(OPh)5(OH) (2), N3P3(OMe)5(OH) (3) and gem-N3P3(NHBut)2(OMe)2(OH)(4) to give P-O-P bridged cyclophosphazenes, [N3P3(OPh)5]2O (5), [N3P3(OPh)5]O[N3P3(OMe)5] (6) and [N3P3(OPh)5]O[N3P3(NHBu')2(OMe)3] (7) respectively. The products are characterised by IR and NMR spectroscopy and mass spectrometry. The P-O-P bridge of compound 5 is readily cleaved by various nucleophiles.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Taylor and Francis Ltd. |
| ID Code: | 17822 |
| Deposited On: | 16 Nov 2010 12:38 |
| Last Modified: | 08 Jun 2011 07:10 |
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