Ganesan, M. ; Krishnamurthy, S. S. ; Nethaji, M. ; Raghuraman, K. (1999) Transition metal chemistry of diphosphazanes and diphosphazane monosulfides Phosphorus, Sulfur, and Silicon and the Related Elements, 147 (1). p. 355. ISSN 1042-6507
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Official URL: http://www.informaworld.com/index/758145004.pdf
Related URL: http://dx.doi.org/10.1080/10426509908053657
Abstract
The reactions of chiral diphosphazanes. Ph2PN((S)-∗CHMePh)PPhY (Y =Ph, N2C3HMe2-3,5) with [CpRu (PPh3)2Cl] and those of the monosulfides, Ph2PN(R)P(S)Ph2 (R = (S)-∗CHMePh or CHMe2) with Ru3(CO)12. [RhCl(cod)]2 and [RhCI(CO)2]2 have been investigated. Molybdenum-palladium heterometallic complexes of the diphosphazanes, MeN(P(OR)2)2 (R = CH2CF3 or Ph) have been synthesised. Some unusual complexes have been obtained by the reductive carbonylation of cobalt and ruthenium halides in the presence of diphosphazanes, RN(PX2)2 (R = Me, X = OCH2CS or OPh; R = CHMe2, X = Ph). The structures of the products have been elucidated by NMR spectoscopy and in some cases confirmed by X-ray crystallography (e.g., 1-4).
| Item Type: | Article |
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| Source: | Copyright of this article belongs to Taylor and Francis Ltd. |
| ID Code: | 17820 |
| Deposited On: | 16 Nov 2010 12:38 |
| Last Modified: | 08 Jun 2011 06:45 |
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