Krishnamurthy, S. S. ; Soundararajan, S. (1967) Antipyrine complexes of rare-earth nitrates Journal of the Less Common Metals, 13 (6). pp. 619-625. ISSN 0022-5088
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002250...
Related URL: http://dx.doi.org/10.1016/0022-5088(67)90107-5
Abstract
Antipyrine complexes of eight rare-earth nitrates of the composition M(C11H12N2O)3 (NO3)3 where M = La, Ce, Pr, Nd, Sm, Gd, Er, and Y, have been prepared by a new, simple method and characterised. The complexes undergo exothermic decomposition at ~300°C. Infrared and U.V. spectral studies of the complexes indicate that antipyrine coordinates to metal through oxygen. The nature of the nitrate bonding is discussed in the light of infrared evidence, and conductivity studies in nitromethane and dimethylformamide.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 17788 |
| Deposited On: | 16 Nov 2010 12:41 |
| Last Modified: | 08 Jun 2011 07:21 |
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