Synthesis and reactivity of a 9-membered azaenediyne: importance of proximity effect in N-alkylation

Roy, Sandip Kumar ; Basak, Amit (2006) Synthesis and reactivity of a 9-membered azaenediyne: importance of proximity effect in N-alkylation Chemical Communications (15). pp. 1646-1648. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2006...

Related URL: http://dx.doi.org/10.1039/B601348A

Abstract

Synthesis of a 9-membered azaenediyne has been achieved for the first time via intramolecular N-alkylation; the importance of proximity of the reacting centres via cobalt carbonyl complexation of the acetylenic moiety and not the activation of propargylic carbon has been demonstrated.

Item Type:	Article
ID Code:	1758
Deposited On:	05 Oct 2010 11:12
Last Modified:	16 May 2016 12:49

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