Jha, Brajesh K. ; Kulkarni, Bhaskar D. (1995) Beckmann rearrangement of cyclohexanone oxime under dilute acidic conditions in micellar media Industrial & Engineering Chemistry Research, 34 (11). pp. 3826-3829. ISSN 0888-5885
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ie00038a020
Related URL: http://dx.doi.org/10.1021/ie00038a020
Abstract
The paper reports the Beckmann rearrangement of cyclohexanone oxime to caprolactam in micellar media under dilute acidic conditions. The anomalous hydrogen ion concentration experienced in the vicinity of the interface can be gainfully exploited to carry out the reaction and change the product pattern. The phase behavior and reaction product distribution at various temperatures and surfactant and acid concentrations are analyzed with a view to optimizing the system performance.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 17383 |
| Deposited On: | 16 Nov 2010 08:25 |
| Last Modified: | 06 Jun 2011 09:34 |
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