Kessar, S. V. (1988) Some new aspects of benzyne and radical mediated cyclisations Proceedings of the Indian Academy of Sciences - Chemical Sciences, 100 (2-3). pp. 217-222. ISSN 0253-4134
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Official URL: http://www.ias.ac.in/j_archive/chemsci/100/1/217-2...
Related URL: http://dx.doi.org/10.1007/BF02839449
Abstract
KNH2/NH3 cyclisations of some alkoxy substituted arylhalides proceed in poor yields. This shortcoming may be overcome by the use of LDA/THF to effect the ring closure which may occur through benzyne or radical intermediates. Besides ortho halogenated dihydroanils and amides, the cyclisation of the benzylamine Schiff bases also provides a convenient route to isoquinoline alkaloids.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Indian Academy of Sciences. |
| Keywords: | Benzyne Intermediates; Radical Intermediates; Cyclisation; Isoquinoline Alkaloids |
| ID Code: | 17227 |
| Deposited On: | 16 Nov 2010 08:10 |
| Last Modified: | 17 May 2016 01:53 |
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