Basak, Amit ; Bag, Subhendu Sekhar ; Bdour, Hussam M. M. (2003) Synthesis and reactivity of enediynyl amino acids and peptides: a novel concept in lowering the activation energy of Bergman cyclisation by H-bonding and electrostatic interactions Chemical Communications, 2003 (20). pp. 2614-2615. ISSN 0009-241X
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Related URL: http://dx.doi.org/10.1039/b308976m
Abstract
Novel enediynyl amino acids and peptides 3 and 5-8 were synthesized and their thermal reactivity towards Bergman cyclization studied and compared with the earlier reported amino acid 4, which demonstrated, for the first time, the effect of H-bonding and electrostatic interactions in lowering the activation energy of Bergman cyclization.
Item Type: | Article |
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Source: | Copyright of this article belongs to The Royal Society of Chemistry. |
ID Code: | 1722 |
Deposited On: | 05 Oct 2010 12:04 |
Last Modified: | 16 May 2016 12:47 |
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