Co(III)DMG complex catalyzed allylation of 1,3-dicarbonyl compounds with allylic alcohols

Mukhopadhyay, Manoj ; Iqbal, Javed (1995) Co(III)DMG complex catalyzed allylation of 1,3-dicarbonyl compounds with allylic alcohols Tetrahedron Letters, 36 (37). pp. 6761-6764. ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/004040...

Related URL: http://dx.doi.org/10.1016/00404-0399(50)1335F-

Abstract

Co(III)DMG, [ Co(III)DMG is Co(DH) (DH2)Cl2, where DH is monoanion of dimethylglyoxime ], complex catalyses the allylation of 1, 3-dicarbonyl compounds with allyl alcohols in good yields. These reactions are highly regioselective as compared to the corresponding Co(II) catalyzed transformation using allyl acetates.

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