Synthesis of a novel cis-proline-derived cyclic type VI β-turn mimic via ring-closing metathesis

Boruah, Anima ; Nageshwar Rao, I. ; Nandy, Jyoti Prokash ; Kiran Kumar, S. ; Kunwar, A. C. ; Iqbal, Javed (2003) Synthesis of a novel cis-proline-derived cyclic type VI β-turn mimic via ring-closing metathesis Journal of Organic Chemistry, 68 (12). pp. 5006-5008. ISSN 0022-3263

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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo020618m

Related URL: http://dx.doi.org/10.1021/jo020618m

Abstract

A cis-proline derived cyclic mimic of a type VI β-turn is synthesized via a ring-closing metathesis reaction. The solution NMR conformational study indicates that the major conformer of the cyclic peptide adopts a type VIa β-turn in CDCl3 and a type VIb β-turn in DMSO-d6.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:16958
Deposited On:16 Nov 2010 13:15
Last Modified:17 Feb 2011 04:52

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