Punniyamurthy, T. ; Bhatia, Beena ; Iqbal, Javed (1994) Cobalt(II)-catalyzed reaction of enolizable aldehydes with alkenes in the presence of dioxygen: the role of acyl radical Journal of Organic Chemistry, 59 (4). pp. 850-853. ISSN 0022-3263
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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo00083a029
Related URL: http://dx.doi.org/10.1021/jo00083a029
Abstract
Complex [bis(salicylidene-N-phenethyl)]cobalt(II) (1) catalyzes the reaction of enolizable aliphatic aldehydes and dioxygen with an electron-deficient alkene to afford the adduct 4 and 5, whereas the reaction with unactivated alkenes leads to the corresponding epoxides 6. These reactions are propose to proceed via a common pathway involving acyl radicals.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 16947 |
| Deposited On: | 16 Nov 2010 13:16 |
| Last Modified: | 17 Feb 2011 05:42 |
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