Chemical weathering in the plain and peninsular sub-basins of the Ganga: impact on major ion chemistry and elemental fluxes

Abstract

Concentrations of major ions, Sr and ⁸⁷Sr/⁸⁶Sr have been measured in the Gomti, the Son and the Yamuna, tributaries of the Ganga draining its peninsular and plain sub-basins to determine their contribution to the water chemistry of the Ganga and silicate and carbonate erosion of the Ganga basin. The results show high concentrations of Na and Sr in the Gomti, the Yamuna and the Ganga (at Varanasi) with much of the Na in excess of Cl. The use of this 'excess Na' (Na = Na_riv - Cl_riv) a common index of silicate weathering yield values of ~18 tons km^-2 yr^-1 for silicate erosion rate (SER) in the Gomti and the Yamuna basins. There are however, indications that part of this Na can be from saline/alkaline soils abundant in their basins, raising questions about its use as a proxy to determine SER of the Ganga plain. Independent estimation of SER based on dissolved Si as a proxy give an average value of ~5 tons km^-2 yr^-1 for the peninsular and the plain drainages, several times lower than that derived using Na. The major source of uncertainty in this estimate is the potential removal of Si from rivers by biological and chemical processes. The Si based SER and CER (carbonate erosion rate) are also much lower than that in the Himalayan sub-basin of the Ganga. The lower relief, runoff and physical erosion in the peninsular and the plain basins relative to the Himalayan sub-basin and calcite precipitation in them all could be contributing to their lower erosion rates. Budget calculations show that the Yamuna, the Son and Gomti together account for ~75% Na, 41% Mg and ~53% Sr and ⁸⁷Sr of their supply to the Ganga from its major tributaries, with the Yamuna dominating the contribution. The results highlight the important role of the plain and peninsular sub-basins in determining the solute and Sr isotope budgets of the Ganga. The study also shows that the anthropogenic contribution accounts for ≤10% of the major ion fluxes of the Ganga at Rajmahal during high river stages (October). The impact of both saline/alkaline soils and anthropogenic sources on the major ion abundances of the Ganga is minimum during its peak flow and therefore the SER and CO₂ consumption rates of the river is best determined during this period.