Basak, Amit ; Roy, Sandip Kumar ; Mandal, Subrata (2004) Activation of macrocyclic enediynes by transannular cyclization Angewandte Chemie International Edition, 44 (1). pp. 132-135. ISSN 1433-7851
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Official URL: http://www3.interscience.wiley.com/journal/1098582...
Related URL: http://dx.doi.org/10.1002/ange.200460831
Abstract
Two N-protected macrocyclic enediynes have been synthesized by intramolecular N-alkylation. The smaller 12-membered enediyne, upon deprotection, yields a stable amine. In contrast, the amine generated from the 13-membered enediyne forms the aminol, which in turn undergoes a spontaneous Bergman cyclization.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
| Keywords: | Cyclization; DNA Damage; Enediynes; Macrocycles |
| ID Code: | 1676 |
| Deposited On: | 05 Oct 2010 09:51 |
| Last Modified: | 13 Jan 2011 10:12 |
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