Evidence for holes on oxygen in some nickel oxides

Ranga Rao, G. ; Hegde, M. S. ; Sarma, D. D. ; Rao, C. N. R. (1989) Evidence for holes on oxygen in some nickel oxides Journal of Physics: Condensed Matter, 1 (11). pp. 2147-2150. ISSN 0953-8984

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Official URL: http://iopscience.iop.org/0953-8984/1/11/026

Related URL: http://dx.doi.org/10.1088/0953-8984/1/11/026

Abstract

Core-level spectroscopic studies show the presence of holes on oxygen in LaNiO3 and LiNiO2 Nickel in these oxides seems to be essentially in the 2+ state instead of the 3+ state-where it would formally be expected to be on the basis of the stoichiometry.

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