Studies in oxasteroids-I : synthesis of 3-cyano-3-methyl-7-methoxychroman-4-one and the structure of an "abnormal" product

Kasturi, T. R. ; Damodaran, K. M. (1996) Studies in oxasteroids-I : synthesis of 3-cyano-3-methyl-7-methoxychroman-4-one and the structure of an "abnormal" product Tetrahedron, 22 (3). pp. 1027-1032. ISSN 0040-4020

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/004040...

Related URL: http://dx.doi.org/10.1016/0040-4020(66)80078-9

Abstract

A synthesis of 3-cyano-3-methyl-7-methoxychroman-4-one is reported. The structure of an "abnormal" product obtained during isomerization (III) with potassium t-butoxide in t-butanol, followed by alkylation with methyl iodide has been proved to be 3-t-butoxy-2-cyano- 2-mehthyl-2',4'-dimethoxypropiophenone (IVa).

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