Kasturi, Tirumalai R. ; Palle, Pragnacharyulu V. P. ; Sattigeri, Jitendra A. ; Kumar, Kaipenchery A. (1996) Novel reduction (Zn-AcOH) of DDHQ esters. A new route to tropone synthesis Tetrahedron, 52 (5). pp. 1707-1712. ISSN 0040-4020
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/004040...
Related URL: http://dx.doi.org/10.1016/0040-4020(95)01006-8
Abstract
Zn/acetic acid reaction of DDHQ esters 1 a-d gave the saturated acids 3 a-d and the hydrocarbons 7 a-d. The intermediacy of the aldehydes 10 and 11 in the formation of the products has been established. Oxidation of hydrocarbons 7a and 7b gave the corresponding tropones (5a and 5b).
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 16074 |
| Deposited On: | 15 Nov 2010 14:15 |
| Last Modified: | 04 Jun 2011 04:19 |
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