Unusual temperature dependence of salt effects for "on water" wittig reaction: hydrophobicity at the interface

Tiwari, Shraeddha ; Anil Kumar, (2008) Unusual temperature dependence of salt effects for "on water" wittig reaction: hydrophobicity at the interface Chemical Communications (37). 4445 - 4447. ISSN 1359-7345

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Official URL: http://www.rsc.org/publishing/journals/CC/article....

Related URL: http://dx.doi.org/10.1039/b809127g

Abstract

An unusual variation with temperature of the salt effects in aqueous Wittig reaction is observed, suggesting that hydrophobic acceleration of reactions comprising on water reactants is fundamentally different from that for reactions with small non-polar solutes.

Item Type:Article
Source:Copyright of this article belongs to Royal Society of Chemistry.
ID Code:1606
Deposited On:05 Oct 2010 12:13
Last Modified:17 May 2011 09:17

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