Hydrophobic effects are dominant over secondary orbital interactions for a simple Diels-Alder reaction in salt solutions

Sarma, Diganta ; Anil Kumar, (2006) Hydrophobic effects are dominant over secondary orbital interactions for a simple Diels-Alder reaction in salt solutions Organic Letters, 8 (10). pp. 2199-2202. ISSN 1523-7060

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol060741q

Related URL: http://dx.doi.org/10.1021/ol060741q

Abstract

The stereoselectivity ratios for a Diels-Alder reaction between cyclopentadiene with methyl trans-crotonate carried out in salt solutions demonstrate the dominance of hydrophobic effects over secondary orbital interactions.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:1600
Deposited On:05 Oct 2010 12:13
Last Modified:12 May 2011 05:36

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