Anil Kumar, ; Deshpande, Suvarna S. (2003) Experimental evidence to support viscosity dependence of rates of Diels-Alder reactions in solvent media Journal of Organic Chemistry, 68 (13). pp. 5411-5414. ISSN 0022-3263
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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo034221%2B?pr...
Related URL: http://dx.doi.org/10.1021/jo034221+
Abstract
This note is aimed at ascertaining whether rates of Diels-Alder reactions depend on the viscosity of solvent media in which the reactions are performed. On the basis of the data collected from the literature and in this laboratory, it is seen in general that the rates increase in the solvents with their viscosities ranging up to ~1.2 cP. In solvents possessing viscosities above 1.2 cP, a drop in the reaction rates is observed in all cases. The effect of temperature on the above phenomena is also examined.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 1593 |
| Deposited On: | 05 Oct 2010 12:14 |
| Last Modified: | 12 May 2011 06:10 |
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