Sreekanth, C. S. ; Hegde, M. S. ; Rao, C. N. R. (1987) An ultraviolet photoelectron spectroscopic study of the electron states of iodine complexes with electron donors Spectrochimica Acta Part A: Molecular Spectroscopy, 43 (4). pp. 471-473. ISSN 0584-8539
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/058485...
Related URL: http://dx.doi.org/10.1016/0584-8539(87)80046-6
Abstract
HeI photoelectron spectra of the vapour phase complexes of diethylether and diethylsulphide with iodine have been investigated for the first time. The iodine orbital ionization energy decreases on complexation while the donor lone-pair orbital ionization energy increases markedly; the shifts are considerably larger in the sulphide complex as expected on the basis of enthalpy considerations.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 15888 |
| Deposited On: | 13 Nov 2010 12:30 |
| Last Modified: | 04 Jul 2012 04:25 |
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