Pradeep, T. ; Hegde, M. S. ; Balakrishna, M. S. ; Krishnamurthy, S. S. (1990) Electronic structures of RN(PX2)2 (R=CH3 or C6H5; X=Cl, OCH3 or OC6H5) ligands: an ultraviolet photoelectron spectroscopic study Journal of Electron Spectroscopy and Related Phenomena, 53 (3). pp. 119-127. ISSN 0368-2048
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/036820...
Related URL: http://dx.doi.org/10.1016/0368-2048(90)80326-6
Abstract
Vapour phase HeI photoelectron spectra of the diphosphazane ligands RN (PX2)2 (R=CH3 or C6H5, X=Cl, OCH3 or OC6H5) are presented along with the assignments of bands on the basis of molecular orbital calculations. The spectra are in accordance with the structural studies which indicate multiple bonding in the P-N-P segment. The phosphorus lone pair ionization energy appears to follow the σ donor ability of the ligands.
| Item Type: | Article |
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| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 15788 |
| Deposited On: | 13 Nov 2010 12:33 |
| Last Modified: | 03 Jun 2011 08:57 |
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