Lumbroso-Bader, N. ; Coupry, C. ; Baron, D. ; Clague, D. H. ; Govil, G. (1975) Dimerization of carboxylic acids: a vapor phase NMR study Journal of Magnetic Resonance, 17 (3). pp. 386-392. ISSN 0022-2364
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002223...
Related URL: http://dx.doi.org/10.1016/0022-2364(75)90207-3
Abstract
Dimerization of acetic and trifluoroacetic acids has been studied, and accurate values of thermodynamic parameters (ΔH and ΔS) and monomer and dimer chemical shifts have been determined. There is some evidence of an inductive effect upon the values of ΔH(-17.5 ± 1.1 kcal mole-1 for acetic acid and -14.5 ± 0.6 for trifluoroacetic acid).
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 15558 |
| Deposited On: | 13 Nov 2010 09:24 |
| Last Modified: | 02 Jun 2011 10:01 |
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