Dhingra, M. M. ; Govil, G. ; Kanekar, C. R. (1971) Contact shifts and mechanism of spin delocalisation in hexa coordianted nickel complexes Chemical Physics Letters, 10 (1). pp. 86-88. ISSN 0009-2614
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/000926...
Related URL: http://dx.doi.org/10.1016/0009-2614(71)80163-X
Abstract
The contact shifts observed for protons of γ-picoline in complexes of the type NiX'2- (γ-picoline)2 (where X = diethyldithiophosphate, ethylxanthate and acetylacetonate) have been studied to understand the spin transfer mechanism. The results indicate that the spin transfer involves not only the highest bonding ligand orbital of σ-symmetry but also to some extent, the lowest antibonding and the highest bonding orbitals of π-symmetry.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 15556 |
| Deposited On: | 13 Nov 2010 09:23 |
| Last Modified: | 02 Jun 2011 10:09 |
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