Dhingra, M. M. ; Govil, G. ; Kanekar, C. R. (1971) Anomalous PMR spectra of cobalt(III) and rhodium(III) NN'-dialkyldithiocarbamates Chemical Physics Letters, 12 (2). pp. 303-305. ISSN 0009-2614
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/000926...
Related URL: http://dx.doi.org/10.1016/0009-2614(71)85070-4
Abstract
A non-equivalence of α-methylene protons has been observed in the proton resonance spectra of cobalt(III) and rhodium(III) NN'-dialkyldithiocarbamates (where alkyl groups are ethyl, n-propyl and benzyl). The spectra are interpreted in terms of hindered rotation about the C---N bond. The barrier to rotation has been found to be 17.0 kcal/mole for the cobalt(III) diethyldithiocarbamate.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 15551 |
| Deposited On: | 13 Nov 2010 09:22 |
| Last Modified: | 02 Jun 2011 10:05 |
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