Hosur, R. V. ; Chary, K. V. R. ; Saran, Anil ; Govil, Girjesh ; Todd Miles, H. (1990) Determination of solution conformation of DNA backbone: application of homonuclear (J, δ) spectroscopy Biopolymers, 29 (6-7). pp. 953-959. ISSN 0006-3525
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/bip.360...
Related URL: http://dx.doi.org/10.1002/bip.360290608
Abstract
Homonuclear two-dimensional (J,δ) proton spectroscopy has been suggested as a method for the measurement of 1H-31P coupling constants in oligonucleotides. The technique has been applied to a dinucleoside monophosphate G2'p5'C and a deoxydecanucleotide d(ACATCGATGT). PCILO energy calculations have been carried out to find minimum energy conformations with respect to the DNA backbone torsion angle ε, and these have been considered for the interpretation of the observed H3'-31P coupling constants in oligonucleotides.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
| ID Code: | 15432 |
| Deposited On: | 13 Nov 2010 08:49 |
| Last Modified: | 02 Jun 2011 09:32 |
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