Srivastava, Santosh K. ; Joshi, Balawant S. ; Newton, M. Gary ; Lee, Doowon ; Pelletier, S. William (1995) Heterolytic fragmentation of deltaline, a norditerpenoid alkaloid Tetrahedron Letters, 36 (4). pp. 519-522. ISSN 0040-4039
Full text not available from this repository.
Official URL: http://linkinghub.elsevier.com/retrieve/pii/004040...
Related URL: http://dx.doi.org/10.1016/0040-4039(94)02300-Z
Abstract
The rearrangement product obtained by treatment of the norditerpenoid alkaloid deltaline (1) with SOCl2 in moist benzene has been assigned structure 5. This compound was also obtained by treatment of 10-chloro-10-deoxydeltaline (4) with aqueous MeOH. However, when (4) was treated with methanolic KOH, a novel rearranged pyrrolidine (8) was obtained. Structures 5 and 8 for these heterolytic fragmentation products were established by nmr spectroscopic data and an X-ray crystal structure determination of 8.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 15085 |
| Deposited On: | 13 Nov 2010 06:49 |
| Last Modified: | 03 Jun 2011 04:19 |
Repository Staff Only: item control page
