Jayannavar, A. M. (1992) Transient behaviour of activationless electronic relaxation in solution Chemical Physics Letters, 199 (1-2). pp. 149-152. ISSN 0009-2614
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/000926...
Related URL: http://dx.doi.org/10.1016/0009-2614(92)80062-G
Abstract
We report a theoretical study of transient behaviour of barrierless electronic reactions in solution. We have generalized the early theory of Oster and Nishijima to the low-friction and small-time domain. An analytical form for the decay of the integrated excited state is derived. We point out the strong friction and temperature dependence of the decay rate in the transient domain.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 14778 |
| Deposited On: | 12 Nov 2010 13:38 |
| Last Modified: | 03 Jun 2011 11:54 |
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