Sandhu, S. S. ; Tandon, S. S. ; Singh, H. (1978) Ligating properties of model bioheterocyclics-II synthesis and characterization of zinc(II) and cadmium(II) halide complexes with 3,6-disubstituted-2,7-dihydro-1,4,5-thiadiazepine derivatives Journal of Inorganic and Nuclear Chemistry, 40 (11). pp. 1967-1970. ISSN 0022-1902
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002219...
Related URL: http://dx.doi.org/10.1016/0022-1902(78)80272-3
Abstract
3,6-Disubstituted-2,7-dihydro-1,4,5-thiadiazepine derivatives (L) with zinc(II) and cadmium(II) halides form complexes of the general formula, [MX2L]nH2O, (X---Cl or I, N = 0, 1, 1) which are non-electrolytes. The far IR and PMR spectra of these complexes indicate their tetrahedral structures with a boat conformation for thiadiazepine ring which coordinates to the metal ions through sulphur and one of the two nitrogen atoms. The thermal studies on these complexes are also reported.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 14765 |
| Deposited On: | 12 Nov 2010 13:40 |
| Last Modified: | 03 Jun 2011 05:09 |
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