Sandhu, Sarjit Singh ; Tandon, Santokh Singh ; Harjit Singh, (1980) Ligating properties of model bioheterocyclics. Part IV. Synthesis and characterization of palladium(II), platinum(II) and platinum(IV) halide complexes with 3,8-Diphenyl-4,5,6,9-tetrahydro1,4,7-thiadiazonines Transition Metal Chemistry, 5 (1). pp. 333-337. ISSN 0340-4285
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Official URL: http://www.springerlink.com/content/p232mp103n54g3...
Related URL: http://dx.doi.org/10.1007/BF01396954
Abstract
Palladium(II) halides form five-coordinate PdC2,(TDAN) complexes with 1,4,7-thiadiazonines (TDAN), whereas platinum(II) chloride yields five coordinate [PtC2,(TDAN)] · n H2O complexes in the solid state and four-coordinate square planar [PtCl(TDAN)]CI · n H2O complexes in DMF solution. Platinum(IV) chloride reacts with TDAN to form six-coordinate [PtCl3(TDAN)]CI · n H2O octahedral complexes. 1.4.7-Thiadiazonine behaves as a tridentate ligand and coordinatesvia all three heteroatoms (S. N and N) forming three mutually adjacent five membered chelate rings with the metal ion.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Springer-Verlag. |
| ID Code: | 14756 |
| Deposited On: | 12 Nov 2010 13:41 |
| Last Modified: | 03 Jun 2011 04:39 |
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