Synthesis and binding character of ether-ester-ethyleneurea podands and macrocycles-synthetic nactin analogs

Kumar, Subodh ; Saini, Rummi ; Harjit Singh, (1992) Synthesis and binding character of ether-ester-ethyleneurea podands and macrocycles-synthetic nactin analogs Tetrahedron Letters, 33 (51). pp. 7937-7940. ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/S0040-4039(00)74783-6

Abstract

The ether-ester macrocycles and podands containing one or two ethyleneurea oxygen(s) as ligating site(s), selectively bind Sr2+ picrate over Li+, Na+, K+, Tl+, Mg2+ and Ca2+ picrates. The sixteen membered macrocycle (4a)- half the size of nactin, shows maximum selectivity towards Sr2+.

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