Optimization of the polycondensation step of polyethylene terephthalate formation with continuous removal of condensation products

Kumar, Anil ; Sharma, Satya N. ; Gupta, Santosh K. (1984) Optimization of the polycondensation step of polyethylene terephthalate formation with continuous removal of condensation products Polymer Engineering & Science, 24 (15). pp. 1205-1214. ISSN 0032-3888

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/pen.760...

Related URL: http://dx.doi.org/10.1002/pen.760241510

Abstract

The polycondensation step of poly(ethylene terephthalate) (PET) formation is assumed to include various side reactions in addition to the usual polymerization reaction. Polymerization in the batch reactor at constant pressure has been modeled to flash volatile components at the end of small discrete time intervals with polymerization occurring during the interval. The Hamiltonian has been written for the time interval and optimum temperature history computed for batch reactors for various reactor pressures. For low pressures, computed optimum temperature history is found to be of similar nature as that used in industry.

Item Type:Article
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ID Code:14292
Deposited On:12 Nov 2010 08:19
Last Modified:02 Jun 2011 09:57

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