Lanthanide doping in metal halide perovskite nanocrystals: spectral shifting, quantum cutting and optoelectronic applications

Abstract

Lanthanides have been widely explored as optically active dopants in inorganic crystal lattices, which are often insulating in nature. Doping trivalent lanthanide (Ln³⁺) into traditional semiconductor nanocrystals, such as CdSe, is challenging because of their tetrahedral coordination. Interestingly, CsPbX₃ (X = Cl, Br, I) perovskite nanocrystals provide the octahedral coordination suitable for Ln³⁺ doping. Over the last two years, tremendous success has been achieved in doping Ln³⁺ into CsPbX₃ nanocrystals, combining the excellent optoelectronic properties of the host with the f-f electronic transitions of the dopants. For example, the efficient quantum cutting phenomenon in Yb³⁺-doped CsPb(Cl,Br)₃ nanocrystals yields a photoluminescence quantum yield close to 200%. Other approaches of Ln³⁺ doping and codoping have enabled promising proof-of-principle demonstration of solid-state lighting and solar photovoltaics. In this perspective article, we highlight the salient features of the material design (including doping in Pb-free perovskites), optical properties and potential optoelectronic applications of lanthanide-doped metal halide perovskite nanocrystals. While review articles on doping different metal ions into perovskite nanocrystals are present, the present review-type article is solely dedicated to lanthanide-doped metal halide perovskite nanocrystals.