Kumar, Anil ; Phukan, Uzzal K. ; Gupta, Santosh K. (1982) Modelling of condensation polymerization of novolac-type phenol-formaldehyde in homogeneous, continuous-flow, stirred-tank reactors Journal of Applied Polymer Science, 27 (9). pp. 3393-3405. ISSN 0021-8995
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/app.198...
Related URL: http://dx.doi.org/10.1002/app.1982.070270917
Abstract
A detailed kinetic model for the novolac-type phenol-formaldehyde polymerization has been proposed in terms of five reactive sites. These sites have been shown to have different reactivities. Mass-balance equations for homogeneous, continuous-flow, stirred tank reactors (HCSTR) for each of the species have been written, and these have been solved numerically. A comparison of the results with those for the batch reactor shows that, for a given residence time, smaller but more polydispersed and branched chains are formed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
| ID Code: | 14193 |
| Deposited On: | 12 Nov 2010 08:53 |
| Last Modified: | 02 Jun 2011 10:02 |
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