Pyrazine based Type‐I sensitizing assemblies for photoreduction of Cu(II) in ‘One‐pot three‐component’ CuAAC reaction under aerial conditions

Kumar, Sourav ; Kumar, Manoj ; Bhalla, Vandana (2021) Pyrazine based Type‐I sensitizing assemblies for photoreduction of Cu(II) in ‘One‐pot three‐component’ CuAAC reaction under aerial conditions Chemistry – An Asian Journal, 16 (23). pp. 3944-3950. ISSN 1861-4728

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Official URL: https://doi.org/10.1002/asia.202101007

Related URL: http://dx.doi.org/10.1002/asia.202101007

Abstract

Photosensitizing assemblies of pyrazine derivative PDA have been developed which exhibit a high photostability, ‘lighted’ excited state, balanced redox potential, high transportation potential and activate oxygen via type-I pathway only. These PDA assemblies in combination with Cu(II) ions catalyze the CuAAC reaction via in situ reduction of Cu(II) ions without any reducing or stabilizing agent. The present protocol has wide substrate scope with recyclability of the catalytic system up to six catalytic cycles and is applicable to gram-scale synthesis.

Item Type:Article
Source:Copyright of this article belongs to John Wiley & Sons, Inc.
ID Code:141705
Deposited On:10 Dec 2025 15:38
Last Modified:10 Dec 2025 15:38

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