A new strategy towards the synthesis of a room-temperature discotic nematic liquid crystal employing triphenylene and pentaalkynylbenzene units

Gupta, Monika ; Gupta, Santosh Prasad ; Rasna, M. V. ; Adhikari, Debashis ; Dhara, Surajit ; Pal, Santanu Kumar (2017) A new strategy towards the synthesis of a room-temperature discotic nematic liquid crystal employing triphenylene and pentaalkynylbenzene units Chemical Communications, 53 (21). pp. 3014-3017. ISSN 1359-7345

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Official URL: https://doi.org/10.1039/C6CC09509G

Related URL: http://dx.doi.org/10.1039/C6CC09509G

Abstract

A new approach is reported for the design of a room-temperature discotic nematic (ND) liquid crystal (LC) dimer consisting of a triphenylene and a pentaalkynylbenzene unit linked via flexible alkyl spacers. The formation of the ND phase is realized most likely through folding of the dimeric molecule that prevent stacking between the triphenylene units, as suggested by modelling in the mesophase derived from X-ray scattering results and high-level DFT calculations.

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