Gadenne, Benoît ; Hesemann, Peter ; Polshettiwar, Vivek ; Moreau, Joël J. E. (2006) Highly ordered functional organosilicas by template‐directed hydrolysis‐polycondensation of chiral camphorsulfonamide precursors European Journal of Inorganic Chemistry, 2006 (18). pp. 3697-3702. ISSN 1434-1948
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Official URL: https://doi.org/10.1002/ejic.200600287
Related URL: http://dx.doi.org/10.1002/ejic.200600287
Abstract
Trialkoxysilylated camphorsulfonamides have been used for the synthesis of functional organosilicas in a template-directed hydrolysis-polycondensation with tetraethylorthosilicate (TEOS). The sol–gel transformation leading to the formation of highly ordered materials indicates that trialkoxysilylated camphorsulfonamides allow the synthesis of functional organosilicas with high structural regularity. This behaviour arises from the affinity of the chiral precursors towards the lyotropic phase of the ionic surfactants in the aqueous hydrolysis-polycondensation mixture.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley & Sons, Inc. |
| ID Code: | 140533 |
| Deposited On: | 24 Dec 2025 09:42 |
| Last Modified: | 24 Dec 2025 09:42 |
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